Stability limits and transformation pathways ofα-quartz under high pressure
نویسندگان
چکیده
منابع مشابه
Transformation pathways of silica under high pressure.
Network-forming oxides with rigid polyhedral building blocks often possess significant capacity for densification under pressure owing to their open structures. The high-pressure behaviour of these oxides is key to the mechanical properties of engineering materials and geological processes in the Earth's interior. Concurrent molecular-dynamics simulations and first-principles calculations revea...
متن کاملMineralogical Notes Transformation Mechanism between High - Quartz and Keatite Phases
As announced in the Amer. M'inerol. 55, 1080 (1970) the summer meeting of the A.C.A. included a Special Session on Mineralogical Crystallography. Fifteen papers were given in a full-day session; abstracts are printed below. In a brief discussion at the end of the day the participants, who included the presidents of the A.C.A., M.A.C., and M.S.A., voted unanimously that the Session on Mineralogi...
متن کاملUniversal elastic-hardening-driven mechanical instability in α-quartz and quartz homeotypes under pressure
As a fundamental property of pressure-induced amorphization (PIA) in ice and ice-like materials (notably α-quartz), the occurrence of mechanical instability can be related to violation of Born criteria for elasticity. The most outstanding elastic feature of α-quartz before PIA has been experimentally reported to be the linear softening of shear modulus C44, which was proposed to trigger the tra...
متن کاملHIGH-PRESSURE CRYSTAL CHEMISTRY AND AMORPHIZATION OF e-QUARTZ
Single-crystal X-ray diffraction experiments on e-quartz at pressures to 15 GPa reveal structural instabilities that result in its gradual transition to an amorphous state. With increasing pressure the average Si-O distance ( ~ 1.61 + 0.01/~) and S i O 4 tetrahedral volume (,,~2.14 ___ 0.02.~ 3) remain constant. Compression of e-quartz results from a dramatic decrease in Si-O-Si angle and corre...
متن کاملHigh-pressure elasticity of alpha-quartz: instability and ferroelastic transition
The single-crystal elastic moduli of alpha-quartz were measured to above 20 GPa in a diamond-anvil cell by Brillouin spectroscopy. The behavior of the elastic moduli indicates that the high-pressure phase transition in quartz is ferroelastic in nature and is driven by softening of C44 through one of the Born stability criteria. The trends in elastic moduli confirm theoretical predictions, but t...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Physical Review B
سال: 2017
ISSN: 2469-9950,2469-9969
DOI: 10.1103/physrevb.95.104112